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2020

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09

Detailed white corundum crystal block structure particle size analysis method.


The production process of smelting of white corundum, due to the refining of alumina solution is not uniform, so the chemical composition and structure of the crystal block parts are uneven. This uneven situation is clearly visible in the broken white corundum crystal block. In the white corundum crystal block, due to the difference in appearance, structure and mineral composition, it can be divided into the following parts: the so-called upper rise, the bottom, the center, the edge and the bottom.,

The crystal block structure of white corundum is that the upper caving material is compact, porous, and the color is from light gray to dark gray, with various colors of pollution. Part of the surface is reddish brown, take the bottom is showing spongy and other grain structure, the color is rose, blue, a few are purple brown. The overall structure of white corundum is porous and dense granular structure with fine crystal. The central bulk of the white corundum crystal block is dense, mostly medium and fine crystalline. With grease luster. The color varies from purplish brown to rose brown. There are ferroalloy inclusions in the block, and light yellow in the silvery section. The edge structure of the white corundum crystal block is dense, mostly fine crystals, some places are medium, occasionally coarse crystals, the structure is not uniform, the section is rough, dull, occasionally with grease, the color is from dark brown to blue black, the bottom of the white corundum crystal block is generally dense, the structure is distributed from fine crystals to coarse crystals, mostly coarse crystals, with a large number of iron alloy inclusions of different sizes.

The structure of white corundum crystal block is very complex, is divided into 5 parts, each part of the structure, color and particle size are not the same, the study of white corundum crystal block structure will help people more clearly understand the white corundum abrasive wear resistance, self-sharpening, toughness and other properties, so as to lay the foundation for the research and development of new types of white corundum abrasive.

White corundum particle size analysis methodScreening method

Advantages: simple, intuitive, low cost of equipment, commonly used in samples greater than 40um

Disadvantages: The results are greatly affected by human factors and mesh deformation.

2. microscope (image) method

Advantages: simple, intuitive, can be morphological analysis, suitable for narrow distribution (and small particle size ratio of less than 10:1) samples.

Disadvantages: poor representativeness, analysis of samples with a wide distribution range is more troublesome, and samples less than 1um cannot be analyzed.

3. settlement method (including gravity settlement and Li Xin settlement)

Advantages: operation gradient, the instrument can run continuously, the price is low, the accuracy and repeatability are good, and the test range is wide.

Disadvantages: the test time is longer, the operation is more cumbersome.

4. resistance method.

Advantages: operation gradient can be measured the number of particles, such as the concept of clear, fast, good accuracy.

Disadvantages: It is not suitable for measuring particle samples less than 0.1um, and it is troublesome to replace the small hole tube for samples with wide particle size distribution.

V. Laser method.

Advantages: simple operation, fast test speed, wide test range, good repeatability and accuracy, online measurement and dry measurement.

Disadvantages: The results are greatly affected by the distribution model, the cost of the instrument is high, and the resolution is low.

6. electron microscopy.

Advantages: suitable for testing ultra-new particles and even nanoparticles, high resolution, can be used for morphological and structural analysis,

Disadvantages: few samples, poor representation, measurement is easily affected by human factors, and the instrument is expensive.

7. light blocking method.

Advantages: The test is convenient and fast, the number of particles in liquid or gas can be measured, and the resolution is high.

Disadvantages: It is not suitable for samples with particle size less than 1umde. It is more exquisite in system. It is only suitable for measuring dust, pollutants or diluted drugs, and not much for general powder.

8. ventilation method.

Advantages: low instrument price. There is no need to disperse the sample, and the measurable material powder can be measured.

Disadvantages: only the average particle size value can be obtained, and the particle size distribution can not be measured.

9. X-ray small angle scattering method

Particle size measurement for nanoparticles.

X. Photon correlation spectroscopy (dynamic light scattering)

Particle size measurement for nanoparticles.


RELATED INFORMATION

Fused white corundum, dense corundum (tabular corundum), brown corundum. These three are all aluminum raw materials. Fused white corundum is calcined alumina or industrial alumina as raw material, high temperature melting in the electric arc furnace, white, block material, crystal for the strip and rhombus, and often the skeleton of the crystal. Because the raw material is very pure, no chemical reaction occurs in the electric furnace operation, but the temperature of the molten liquid, the cooling rate, etc. have a great influence on the structure of the block. Fused white corundum, dense corundum (tabular corundum), brown corundum. These three are all aluminum raw materials. Aluminum content Dense corundum and white corundum reached 99%, brown corundum aluminum content: 95%. Price, dense corundum higher than white corundum White corundum is higher than brown corundum. So in the application of refractory materials, dense corundum is better than white corundum, brown corundum ranked third
Magnesium aluminate spinel is widely used in steel-making refractories due to its special properties of slag corrosion resistance, good thermal shock resistance and high strength at high temperature. High quality pre-fit The preparation of spinel provides a new raw material for the production of amorphous and shaped high purity refractories. The two main methods for the synthesis of spinel are sintering and electrofusion. Most spinel materials are made from high-purity synthetic alumina and chemical grade magnesia, That is, sintering in a shaft kiln and electromelting in an electric arc furnace. The advantage of sintering magnesium aluminate spinel is that the process is a continuous ceramization process, controlling the feed in the kiln. Velocity and uniform temperature distribution, resulting in a very uniform crystal size of 30-80 μm and low porosity (<3%) of the product. Electromelting production of magnesium aluminum spinel is a representative intermittent operation, large casting blocks need to extend the cooling time, the cooling of the casting block leads to microstructure. Uneven, due to faster cooling, the outer spinel crystals are smaller than the inner ones, and the low melting point impurities are concentrated in the center. Therefore, it is necessary Spinel raw materials are sorted and homogenized. Another advantage of using high-purity raw materials to produce aluminum magnesium spinel is the low impurity content in the aluminum magnesium spinel aggregate (MgO A1203>99%), especially SiO2 The low content makes it have good high temperature performance. Alumina-based aluminum magnesium spinel has no good performance as synthetic alumina-based aluminum magnesium spinel and can only be used Corrosion resistance and high temperature strength requirements are not high parts.
Magnesium aluminate spinel has excellent properties, such as high melting point (2135), high hardness (16GPa), low thermal expansion, high corrosion resistance and excellent optical properties. Widely used in refractory materials, humidity sensors, transparent ceramic materials, anode materials, artificial flange materials and catalytic materials.
Bauxite-based sintered magnesium aluminate spinel uses high-quality bauxite with Al2O3 content of more than 76% and high-quality light burned magnesium powder with MgO content of more than 95%. In an ultra-high temperature tunnel kiln, it is sintered at a high temperature above 1800°C. Bauxite-based sintered magnesium aluminate spinel uses high-quality bauxite with Al2O3 content of more than 76% and high-quality light burned magnesium powder with MgO content of more than 95%. The chemical process is sintered at a high temperature above 1800°C in an ultra-high temperature tunnel kiln, with high volume density, high mineral phase content, good grain development and structure. Uniform, stable quality. Magnesium aluminate spinel has good corrosion resistance, corrosion, peeling ability, good slag resistance, abrasion resistance, thermal shock stability Good, high temperature resistance and other performance characteristics. It is the production of refractory products such as magnesium aluminum spinel bricks, ladle lining bricks, ladle castables and other refractory products for the high-temperature zone of cement rotary kilns. Ideal raw materials. Magnesium aluminate spinel is widely used in refractory materials, iron and steel smelting, cement rotary kiln and glass industrial kiln It has good erosion resistance, abrasion resistance and good thermal shock stability. Its main purpose: one is to replace the magnesium chrome sand manufacturing magnesium aluminum spinel brick Used in cement rotary kiln, not only to avoid chromium pollution, but also has good resistance to spalling; the second is used to make ladle castable, greatly improving the steel plate Lining resistance to erosion. It is widely used in steel-making refractory materials. Preparation of high-quality pre-synthesized spinel for amorphous and shaped high-purity refractories The production of new raw materials